According to the polarization study 3-ATA acts as a
mixed type inhibitor since Ecorr values do not change significantly
in the presence of 3-ATA, whereas cathodic
Tafel slopes exhibit changes. The positive shift in the
values of Ecorr indicated that 3-ATA-Q acts as anodic
inhibitor. As can be seen from Tables 3 and 4, the inhibition
efficiencies and the degree of surface coverage
increase with increasing concentrations of 3-ATA and
3-ATA-Q. However, in the case of 4-HQ, the corrosion
current densities increase with increasing concentrations.
The adsorption of inhibitor molecules from an aqueous
solution can be regarded as a quasi-substitution process
between the organic compound in the aqueous phase,
Org(aq), and water molecules at the electrode surface,
H2O(s):
OrgeaqT t xH2OesTOrgesT t xH2OeaqT e3T
where x is the size ratio indicating the number of water
molecules displaced by one molecule of organic inhibitor.
The adsorption isotherms provide important information
for determining the mechanism of organoelectrochemical
reactions. The most common isotherms are
those developed by Langmuir, Frumkin, Hill de Boer,
Parsons, Damaskin-Parsons, Temkin, Kastening Holleck,
Flory-Huggins, Dhar-Flory Huggins, Bockris-Swinkels
and El-Awady et al.
如果是好的翻译我会追加分数的，翻译器翻译的是
Ecorr值不随着3-ATA变化，因此3-ATA作混合型抑制剂。而阴极Tafel斜率展览的变化。积极转变价值Ecorr指出，3-ATA标准的调Q作为阳极抑制剂。可以看出，从表3和第4的抑制作用 效率和程度的表面覆盖 随着浓度的增加3 - ATA和 3 - ATA标准- Q报告。然而，在案件4总部，腐蚀 电流密度的增加而增加的浓度。 吸附抑制剂分子从水 解决方案可被视为一个准替代进程 之间的有机化合物在水相， 组织（ aq ）的，与水分子在电极表面，水（补）： OrgeaqT t xH2OesT ？ OrgesT t xH2OeaqT e3T 其中x是大小比例，说明一些水 分子流离失所的一个分子的有机抑制剂。 的吸附等温线提供了重要信息 确定机制organoelectrochemical 反应。最常见的等温线的 所开发的朗格姆尔，弗兰坎，希尔伊沃德布尔， 帕森斯， Damaskin -帕森斯，特姆金， Kastening Holleck ， 弗洛里，哈金斯，达尔-弗洛里哈金斯， Bockris ，斯温克尔斯 和El -阿瓦迪等。
请参考其给予我答案。。。谢谢
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